Origin of the ocean on the Earth: Early evolution of water D/H in a hydrogen-rich atmosphere

The origin of the Earthʹs ocean has been discussed on the basis of deuterium/hydrogen ratios (D/H) of several sources of water in the Solar System. The average D/H of carbonaceous chondrites (CCʹs) is known to be close to the current D/H of the Earthʹs ocean, while those of comets and the solar nebula are larger by about a factor of two and smaller by about a factor of seven, respectively, than that of the Earthʹs ocean. Thus, the main source of the Earthʹs ocean has been thought to be CCʹs or adequate mixing of comets and the solar nebula. However, those conclusions are correct only if D/H of water on the Earth has remained unchanged for the past 4.5 Gyr. In this paper, we investigate evolution of D/H in the ocean in the case that the early Earth had a hydrogen-rich atmosphere, the existence of which is predicted by recent theories of planet formation no matter whether the nebula remains or not. Then we show that D/H in the ocean increases by a factor of 2–9, which is caused by the mass fractionation during atmospheric hydrogen loss, followed by deuterium exchange between hydrogen gas and water vapor during ocean formation. This result suggests that the apparent similarity in D/H of water between CCʹs and the current Earthʹs ocean does not necessarily support the CCʹs origin of water and that the apparent discrepancy in D/H is not a good reason for excluding the nebular origin of water.