Detection of C2HD and the D/H ratio on Titan

We report here the first detection of mono-deuterated acetylene (acetylene-d1, C2HD) in Titanʹs atmosphere from the presence of two of its emission bands at 678 and 519 cm−1 as observed in CIRS spectral averages of nadir and limb observations taken between July 2004 and mid-2007. By using new laboratory spectra for this molecule, we were able to derive its abundance at different locations over Titanʹs disk. We find the C2HD value ( 1.27 −0.22 −0.13 × 10 −9 ) to be roughly constant with latitude from the South to about 45° N and then to increase slightly in the North, as is the case for C2H2. Fitting the 678 cm−1 ν 5 band simultaneously with the nearby C2H2 729 cm−1 ν 5 band, allows us to infer a D/H ratio in acetylene on Titan with an average of the modal values of 2.09 ± 0.45 × 10 −4 from the nadir observations, the uncertainties being mainly due to the vertical profile used for the fit of the acetylene band. Although still subject to significant uncertainty, this D/H ratio appears to be significantly larger than the one derived in methane from the CH3D band (upper limit of 1.5 × 10 −4 ; Bézard, B., Nixon, C.A., Kleiner, I., Jennings, D.E., 2007. Icarus, 191, 397–400; Coustenis, A., Achterberg, R., Conrath, B., Jennings, D., Marten, A., Gautier, D., Bjoraker, G., Nixon, C., Romani, P., Carlson, R., Flasar, M., Samuelson, R.E., Teanby, N., Irwin, P., Bézard, B., Orton, G., Kunde, V., Abbas, M., Courtin, R., Fouchet, Th., Hubert, A., Lellouch, E., Mondellini, J., Taylor, F.W., Vinatier, S., 2007. Icarus 189, 35–62). From the analysis of limb data we infer D/H values of 9.6 −3.1 −4.5 × 10 −5 (at 54° S), 2.4 −0.7 −0.9 × 10 −4 (at 15° S), 2.7 −0.6 −0.7 × 10 −4 (at 54° N) and 1.9 −0.5 −0.7 × 10 −4 (at 80° N), which average to a mean value of 1.63 ± 0.27 × 10 −4 .