Methane and its isotopologues on Saturn from Cassini/CIRS observations

High spectral resolution observations from the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169–297] are analysed to derive new estimates for the mole fractions of CH4, CH3D and 13CH4 of ( 4.7 ± 0.2 ) × 10 −3 , ( 3.0 ± 0.2 ) × 10 −7 and ( 5.1 ± 0.2 ) × 10 −5 respectively. The mole fractions show no hemispherical asymmetries or latitudinal variability. The analysis combines data from the far-IR methane rotational lines and the mid-IR features of methane and its isotopologues, using both the correlated-k retrieval algorithm of Irwin et al. [Irwin, P., and 9 colleagues, 2008. J. Quant. Spectrosc. Radiat. Trans. 109, 1136–1150] and a line-by-line approach to evaluate the reliability of the retrieved quantities. C/H was found to be enhanced by 10.9 ± 0.5 times the solar composition of Grevesse et al. [Grevesse, N., Asplund, M., Sauval, A., 2007. Space Sci. Rev. 130 (1), 105–114], 2.25 ± 0.55 times larger than the enrichment on Jupiter, and supporting the increasing fractional core mass with distance from the Sun predicted by the core accretion model of planetary formation. A comparison of the jovian and saturnian C/N, C/S and C/P ratios suggests different reservoirs of the trapped volatiles in a primordial solar nebula whose composition varies with distance from the Sun. This is supported by our derived D/H ratio in methane of ( 1.6 ± 0.2 ) × 10 −5 , which appears to be smaller than the jovian value of Lellouch et al. [Lellouch, E., Bézard, B., Fouchet, T., Feuchtgruber, H., Encrenaz, T., de Graauw, T., 2001. Astron. Astrophys. 370, 610–622]. Mid-IR emission features provided an estimate of C 12 / C 13 = 91.8 −7.8 +8.4 , which is consistent with both the terrestrial ratio and jovian ratio, suggesting that carbon was accreted from a shared reservoir for all of the planets.