Particle size and abundance of HC3N ice in Titan’s lower stratosphere at high northern latitudes

Up to now, there has been no corroboration from Cassini CIRS of the Voyager IRIS-discovery of cyanoacetylene (HC3N) ice in Titan’s thermal infrared spectrum. We report the first compelling spectral evidence from CIRS for the ν6 HC3N ice feature at 506 cm−1 at latitudes 62°N and 70°N, from which we derive particle sizes and column abundances in Titan’s lower stratosphere. We find mean particle radii of 3.0 μm and 2.3 μm for condensed HC3N at 62°N and 70°N, respectively, and corresponding ice phase molecular column abundances in the range 1–10 × 1016 mol cm−2. Only upper limits for cloud abundances can be established at latitudes of 85°N, 55°N, 30°N, 10°N, and 15°S. Under the assumption that cloud tops coincide with the uppermost levels at which HC3N vapor saturates, we infer geometric thicknesses for the clouds equivalent to 10–20 km or so, with tops at 165 km and 150 km at 70°N and 62°N, respectively.