Author/Authors :
Yang, Xiaomei College of Chemistry and Molecular Engineering - Zhengzhou University - Zhengzhou, People’s Republic of China , Fu, Xiaomin College of Chemistry and Molecular Engineering - Zhengzhou University - Zhengzhou, People’s Republic of China , Bu, Ningning Research Center of Heterogeneous Catalysis and Engineering Sciences - School of Chemical Engineering and Energy - Zhengzhou University, Zhengzhou, People’s Republic of China , Han, Li Research Center of Heterogeneous Catalysis and Engineering Sciences - School of Chemical Engineering and Energy - Zhengzhou University, Zhengzhou, People’s Republic of China , Wang, Jianfeng Research Center of Heterogeneous Catalysis and Engineering Sciences - School of Chemical Engineering and Energy - Zhengzhou University, Zhengzhou, People’s Republic of China , Song, Chengying Research Center of Heterogeneous Catalysis and Engineering Sciences - School of Chemical Engineering and Energy - Zhengzhou University, Zhengzhou, People’s Republic of China , Su, Yunlai College of Chemistry and Molecular Engineering - Zhengzhou University - Zhengzhou, People’s Republic of China , Zhou, Lipeng College of Chemistry and Molecular Engineering - Zhengzhou University - Zhengzhou, People’s Republic of China , Lu, Tianliang Research Center of Heterogeneous Catalysis and Engineering Sciences - School of Chemical Engineering and Energy - Zhengzhou University, Zhengzhou, People’s Republic of China
Abstract :
Cu–Ni/γ-Al2O3 bimetallic catalysts were developed for anaerobic dehydrogenation of non-activated primary aliphatic alcohols to aldehydes. Systematic investigation about the promotion effect of nickel on the catalytic performance was carried out. Hydrogenation of C=C bond rather than C=O bond, was significantly improved over Cu–Ni/γ-Al2O3 catalyst by introducing nickel, which interprets the good conversion of primary aliphatic alcohols. This work would contribute to design new catalysts for dehydrogenation of primary aliphatic alcohols.
