Author/Authors :
Farhadipour, Abolghasem Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad, Mashhad , Eshghi, Hossein Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad, Mashhad , Alizadeh, Mohammad Hassan Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad, Mashhad , Yousefi, Mozhde Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad, Mashhad , Artetxe, Beñat Departamento de Química Inorgánica - Facultad de Ciencia y Tecnología - Universidad del País Vasco UPV/EHU, Bilbao, Spain , Gutiérrez-Zorrilla, Juan M Departamento de Química Inorgánica - Facultad de Ciencia y Tecnología - Universidad del País Vasco UPV/EHU, Bilbao, Spain
Abstract :
Two new Melamine-Keggin hybrid nanorods, MELH-PMo12 and MELH-PW12, for the first time are successfully synthesized by two chemical methods, one-step solid-state chemical reaction method and experimental solvent diffusion method at room temperature. One-step solid-state reactions involve grounded nanorod materials along with grinding of row material and with solvent diffusion method these nanorods synthesized in single crystals form. These compounds crystallized in trigonal space groups P-3. Elemental analysis, infrared spectroscopy, UV spectroscopy and XRD analysis results prove that the samples still possess Keggin type structure. Transmittance electron microscopy and single-crystal X-ray have shown that the samples have nanorod structures.
Keywords :
Solid-state reaction , Cluster compound , Organic–inorganic hybrid , Solvent diffusion , Nanostructure
