Title of article :
Nanoparticles Poly Ethylene Imine-Functionalized MCM- as a Solid Catalyst for Multi-Component Reactions
Author/Authors :
Hamadi, Hosein Department of Chemistry - College of Science - ShahidChamran University, Ahvaz, Iran , Gholami, Maryam Department of Chemistry - College of Science - ShahidChamran University, Ahvaz, Iran , Khoobi, Mehdi Department of Medicinal Chemistry - Faculty of Pharmacy and Pharmaceutical Sciences Research Center - Tehran University of Medical Sciences, Iran
Abstract :
A novel magnetically immobilized polyethyleneimine (PEI) fabricated by covalently anchoring on MCM-41 (MCM-41@PEI) was prepared. The synthesized catalyst was characterized by Fourier transform infrared (FT-IR), thermogravimetric analysis (TGA), X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The immobilized PEI was shown to be an efficient heterogeneous catalyst for the synthesis of spiro-oxindole and benzopyranes derivatives via multi-component reaction (MCR), in ethylene glycol as a green solvent. No leaching problem was observed after several runs, while the catalyst can be recovered and reused without loss of reactivity under the described reaction conditions.
Keywords :
benzopyranes , spiro-oxindole , MCM-41 supported catalyst , Microwave , Catalyst , Polyethylenimine
Journal title :
Astroparticle Physics
