Title of article
conformational properties and the anomeric effect study of phosphinanes
Author/Authors
Azizian, Javad Department of chemistry - Science and Reaserch branch Islamic azad university, Tehran, Iran , Entezari, Mahdieh Department of chemistry - Mahshahr branch Islamic azad university, Mahshahr, Iran , Anaraki Ardakani, Hossein Department of chemistry - Mahshahr branch Islamic azad university, Mahshahr, Iran , Zomorodbakhsh, Shahab Department of chemistry - Mahshahr branch Islamic azad university, Mahshahr, Iran
Pages
8
From page
25
To page
32
Abstract
Abstract -Ab initio HF/6-31G* Methode was employed to calculate the
bond length in 2- phosphinanes when electronegative groups was at C-2
tend axial and equatorial positions. The magnitude of the anomeric
effect depends on the nature of the substituent, the effect of the
substituent can be seen by comparing the bond length in 2-chloro and 2-
boromo substituented phosphinanes. The effect of anomeric effect have
been effected on the bond length in 2- phosphinanes.
Keywords
Ab initio calculations , axial and equatorial position , bond length , 2- phosphinane , anomeric effect
Journal title
Astroparticle Physics
Serial Year
2014
Record number
2428246
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