Title of article :
Conductometric study of the complex formation of Rb+, Cs+, NH4 +, K+, Tl+ and Ag+ ions with several crown ethers in acetonitrile-dimethylsulfoxide and acetonitrile-dimethylformamide binary mixtures
Author/Authors :
Ghasemi, Jahan B Chemistry Department - Faculty of Sciences - K.N. Toosi University of Technology , Babaee, Elaheh Chemistry Department - Faculty of Sciences - Razi University , Khavarian, Fakhredin Chemistry Department - Faculty of Sciences - Razi University
Abstract :
The nanocomposites of poly (Acryl amide-co-Acrylic acid) with different contents of NaA
zeolite were prepared using ammonium persulfate as an initiator and N, N′-methylene
bisacrylamide as the crosslinker. The morphology was characterized by SEM and the structure of
nanocomposite materials was studied with XRD and FT-IR that showed the interaction between
porous materials and poly (AAm-co-Aac). The adsorption behaviors of methylene blue were
investigated for nanocomposites. It was shown that poly (AAm-co-AAc)/NaA nanocomposites
have higher adsorption than NaA and poly (AAm-co-AAc) alone. This effect was attributed to
good interaction between the hydroxyl group in porous materials and carboxylic group in poly
(AAm-co-AAc) with methylene blue.
Keywords :
Cs+ , Rb+ , NH4 + , T1+ , K+ , Ag+ , complexes , Conductance , Mixed solvents
Journal title :
Astroparticle Physics