Title of article :
Synthetic Application of Magnetic Nanocomposite Fe3O4@PEG-Au as a Heterogeneous and Reusable Nanocatalyst in The Suzuki Coupling Reactions
Author/Authors :
Homayoun Keihan, Amir Baqiyatallah University of Medical Sciences, Tehran , Veisi, Hamed Baqiyatallah University of Medical Sciences, Tehran , Javaheri, Hadis Department of Chemistry - Payame Noor University, Tehran
Abstract :
In the present study, we carried out chemical synthesis and characterization of Fe3O4@PEG-Au
as a magnetic nanocomposite in aqueous solution by chemical co-precipitation of Fe3+ and Fe2+
ions and encapsulated by poly (ethylene glycol) (PEG) in order to enhancing hydrophilicity,
biocompatibility and immobilizing gold ions in the presence of NaBH4 as a reducing agent.
Nanostructures were characterized again with FESEM and TEM. The nanoparticles with their
spherical shape and dimensions of approximately 12 nm were used as a heterogeneous
catalyst for Suzuki coupling reactions whilst in mild conditions. The high efficiency of the
catalytic reaction was affirmed by the good yields of products, easy work-up, and absence of
leached gold from the support and the smooth recovery of the catalyst.
Keywords :
Nanocatalyst , Suzuki , Magnetic , PEG , Gold NPs
Journal title :
Astroparticle Physics