Title of article :
The Effect of Hydrogen Bonding and ~–~ Stacking to Stabilization of 3D Networks of a New Proton Compound, (a-6-mpyH)(Hpyzd) H2O
Author/Authors :
Mohammadinasab, R Department of Chemistry - Science and Research Branch - Islamic Azad University, Tehran , Tabatabaee, M Department of Chemistry - Yazd Branch - Islamic Azad University, Yazd , Seyed Sadjadi, M. A Department of Chemistry - Science and Research Branch - Islamic Azad University, Tehran
Abstract :
A new proton transfer compound, formulated as (Hamp-6-pic)(Hpyzd) ·H2O (1), has been
synthesized from the reaction of pyrazine-2,3-dicarboxylic acid (H2pyzd) and 2-amino-6-methyl
pyridine (amp-6-pic), in 1:1 molar ratio. Extensive O-H...O, N-H...N and O-H...O hydrogen bonds
involving (Hamp-6-pic)+ cation, (Hpyzd)- anion and co-crystal water molecule, static electronic, and
~…~ stacking interactions form a three-dimensional network.
Keywords :
(Hamp-6-pic)(Hpyzd).H2O , proton transfer , hydrogen bonds , ~…~ stacking
Journal title :
Astroparticle Physics
