Author/Authors :
Mohammadzadeh Asl, S Bioengineering Group - Nanotechnology and Advanced Materials - Materials and Energy Research Center - (MERC), Tehran , Ganjali, M Bioengineering Group - Nanotechnology and Advanced Materials - Materials and Energy Research Center - (MERC), Tehran , Alizadeh, M Department of Materials Engineering - Isfahan University of Technology , Shahlaei, M Bioengineering Group - Nanotechnology and Advanced Materials - Materials and Energy Research Center - (MERC), Tehran , Sohrabi Jam, A Bioengineering Group - Nanotechnology and Advanced Materials - Materials and Energy Research Center - (MERC), Tehran
Abstract :
316L stainless steel is the most commonly used metallic material in the
manufacture of orthopedic implants. To achieve better properties metal
implants are often coated with biocomposites. A sol–gel method was used for
coating Poly lactic acid (PLA)/Hydroxyapatite nanopowder (nHA) on stainless
steel 316L substrate. 10g PLA was added to 100 gr chloroform and stirred for 2
h at 60 °C. Then 0.5g nHA was added and continued to stir for 30 min at 60 °C
to form a jelly-like solution. Afterwards, the substrate was immersed into the
solution and kept for 2, 5, and 15 minutes and withdrawn from the bath
solution at a prescribed withdrawal velocity. The X-ray diffraction (XRD) and
Fourier transform infrared spectroscopy (FTIR) were utilized in order to
evaluate the phase composition and the functional groups of PLA/nHA
coatings. Morphology and thickness of the nanocomposites coating of samples
were evaluated using scanning electron microscope (SEM). Cell viability asses
and eventually corrosion resistance were evaluated by MTT and potentiostat
test, respectively. SEM result shows that the deposition rate is measured (in
terms of coating thickness) as a function of immersion/soaking time. The
results of XRD and FTIR tests confirmed the presence of phase of PLA/nHA
nanocomposites in the coated samples. Furthermore, the corrosion resistance of
coated samples was increased with immersion or soaking time in the solution
bath of PLA/nHA nanocomposites and was higher than the uncoated sample.
Keywords :
Nano hydroxyapatite , Poly lactic acid , Stainless steel , Dip coating