Silica membrane performance for hydrogen separation from methanol steam reforming products: Assessment of diff erent multistage membrane schemes

The aim of this work is a theoretical study of multistage silica membrane confi gurations for hydrogen purifi cation by methanol steam reforming (MSR) products. Four membrane schemes including single permeator, CMC (continuous membrane column), ISMC (“in series” membrane cascade), and CRC (countercurrent recycle membrane cascade) were considered for this purpose. The modeling results showed that silica membranes have a high potential for high purity (more than 99.9%) hydrogen production. The lowest amounts of compressor duty and the required total membrane area were considered as the objective functions to select the optimal design and amount of hydrogen purifi cation. A comparison of our simulation results of the diff erent multistage membrane schemes showed the CRC confi guration was more effi cient than the other confi gurations. The modeling results show that that increasing the retentate side pressure from 2 to 5 bar reduced the total silica membrane area for the CRC scheme by almost 13 times (30.67 and 2.37 cm2 silica membrane area for a retentate side pressure of 2 and 5 bar, respectively).