PhotoDegradation of Phenol Using TiO2/CMK3 PhotoCatalyst Under Medium Pressure UV Lamp

Phenol is considered as one of the major environmental concerns due to its characteristics including chronic toxicity, biological stability, and increasing the toxicological intermediates after biological degradation. Therefore, the aim of this study was to evaluate the photodegradation of phenol using the titanium dioxide (TiO2) photocatalyst on ordered mesoporous carbon (CMK3) support under UV irradiation. In this study, the effects of some parameters including pH value (4, 5, 6, 7, 8, 9, 10), TiO2/CMK3 concentration (0.05, 0.1, 0.15, 0.3, 0.5 g/L), irradiation time (30, 60, 90, 120, 150 min), and phenol concentration (50, 100, 150 and 200 mg/L) were assessed. The properties of the CMK3 and TiO2/CMK3 were compared using the transmission electron microscopy (TEM), Xray powder diffraction (XRD) and N2 adsorptiondesorption isotherm. The results revealed that the process studied was remarkably affected by the parameters, and the optimum values of the parameters were as follows: pH=6, TiO2/CMK3 concentration =0.15 g/L, phenol concentration = 100 mg/L, and irradiation time=150 min. The phenol degradation efficiency and total organic carbon (TOC) removal efficiency for phenol were 96% and 74%, respectively. Moreover, the stability greater than 7 times for the studied photocatalyst was indicative of its high potential to be used in photodegradation processes for the elimination of pollutants.