Title of article :
Interaction Parameters for CuCl2 Plus Orange G (OG) at 19.1oC Using Carbon Glassy Electrode (CGE) in KCl Aqueous Solutions
Author/Authors :
Gomaa ، Essamhassan G Arafa - Mansoura University , Diab ، Moustafa - Damietta University , Elsonbati ، Adel - Damietta University , Abulenader ، Hamed M - Mansoura University , Helmy ، Asmaa - Damietta University
Abstract :
The redox mechanisms were examined for copper chloride in absence and presence of Orange G (OG) at 19.1°C using Carbon glassy electrode (CGE). The supporting electrolyte used is 0.1 M KCl effect of scan rate was also studies for the redox reactions for CuCl2 alone and in presence of the ligand used orange G (OG). Stability constants for the complex formed from the interaction of CuCl2+ Orange G (OG) were evaluated with the different thermo chemical data. Effect of different scan rates were examined for cupric Chloride in absence and presence of the ligand used Orange G (OG).The different scans used are 0.1, 0.05, 0.02 and 0.01 V/Sec. The stability constants and Gibbs free energies of complexation were also estimated for the interaction of CuCl2 with Orange G (OG) in 0.1MKCl supporting electrolyte.
Keywords :
Solvation parameters , Cyclic Voltammetry , copper chloride , orange G (OG) , glassy carbon electrode (CGE)
Journal title :
Asian Journal of Nanoscience and Materials
Journal title :
Asian Journal of Nanoscience and Materials