Title of article :
NanoSized and Single Crystal of a 1D Copper(I) Coordination Polymer: Preparation, Characterization, Thermal and Structural Studies
Author/Authors :
Dehno Khalaji ، Aliakbar - Golestan University , Peyghoun ، Seyyed Javad - Golestan University , Dusek ، Michal Institute of Physic of the Czech Academy of Sciences , Eigner ، Vaclav Institute of Physic of the Czech Academy of Sciences
Abstract :
Nanosized powder of a new 1D copper(I) coordination polymer, [Cu(nba2en)(NCS)]n (1), (nba2en = N,Nʹbis(4ntrobenzylidene)ethane1,2diamine, was synthesized using ultrasonic bath assisted and characterized by scanning electron microscopy (SEM), IR and 1HNMR spectroscopy, and elemental analyses. Thermal stability of 1 was studied using thermogravimetric (TG) and differential thermal analyses (DTA). The crystal structure was investigated by singlecrystal Xray diffraction. The structure of 1 consists of a 1D polymeric chain in which copper(I) ions are bridged by two thiocyanate group bonding in an endtoend fashion, with CuCu separation 5.556(4) Å.
Keywords :
Nanosized , Singlecrystal Xray diffraction , 1D Polymeric chain , crystal structure
Journal title :
Asian Journal of Nanoscience and Materials
Journal title :
Asian Journal of Nanoscience and Materials
