Title of article
Preparation and Crystal Structure Determination of Zinc (II) Bromide Complexes at the Presence of Various Ligands
Author/Authors
Dehno Khalaji ، Aliakbar - Golestan University , Shahsavani ، Ensieh - Payamenoor University , Dusek ، Michal Institute of Physic ASCR , Kucerakova ، Monika Institute of Physic ASCR , Hornfeck ، Wolfgang Institute of Physic ASCR
Pages
9
From page
590
To page
598
Abstract
In this paper, we report the syntheses and crystal structuredetermination of three mononuclear and fourcoordinated zinc(II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and theircrystal structures are investigated by single crystal Xray diffraction. In complex 1, the TSC coordinates to the zinc(II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc(II) ion as a monodentate ligand via S atom. In these complexes, the zinc(II) ion coordinated in a distorted tetrahedral coordination geometry.
Keywords
Zinc(II) , Mononuclear , Distorted tetrahedral
Journal title
Chemical Methodologies
Serial Year
2019
Journal title
Chemical Methodologies
Record number
2462258
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