Title of article
Synthesis of icosadeuteriobenzopinacol (benzopinacol-d20)
Author/Authors
Adjibodé ، Steeve M. - Universitéd Abomey-Calavi, Campus du Champ de Foire , Kasséhin ، Urbain C. - Universitéd Abomey-Calavi, Campus du Champ de Foire , Gbaguidi ، Fernand A. - Universitéd Abomey-Calavi, Campus du Champ de Foire , Poupaert ، Jacques H. - Université catholique de Louvain
Pages
6
From page
36
To page
41
Abstract
This work reports on synthesis of high yield (92%) of isosadeuterio- benzopinacol (benzopinacol-d20) via photo-reductive dimerization of benzophenone-d10. The latter compound was obtained using an improved method to achieve a material with high isotopic purity ( 99%). This material can be served for calibration of mass spectrometric assays. In this study, it was also observed that benzophenone-d10 reacts faster than its natural abundance counterpart. However, elucidating the origin of this phenomenon will require additional work.
Keywords
benzopinacol , d20 , benzophenone , d10 , dimerization , photo , reductive
Journal title
Journal of Medicinal and Chemical Sciences
Serial Year
2020
Journal title
Journal of Medicinal and Chemical Sciences
Record number
2471201
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