Title of article :
Lanthanum cerate (La2Ce2O7): hydrothermal synthesis, characterization and optical properties
Author/Authors :
Khademinia, Shahin Department of Chemistry - Semnan University , Behzad, Mahdi
Abstract :
La2Ce2O7 nano-powders were synthesized via
a hydrothermal reaction in a deionized water (S1) and in a
2 M NaOH aqueous solution (S2) at 180 C for 48 h.
La(NO3)3H2O and (NH4)2Ce(NO3)6 were used in the
stoichiometric 1:1 La:Ce molar ratio as raw materials. The
obtained materials were crystallized in a cubic crystal
structure with space group. The synthesized materials were
characterized by powder X-ray diffraction technique and
Fourier-transform infrared spectroscopy. To investigate the
effect of the basic solution on the morphology of the obtained materials, the morphologies of the synthesized materials were studied by field emission scanning electron
microscopy technique. The technique showed that the
morphology of La2Ce2O7 samples changed from grain to
rod-like structure in presence of the basic solution. Cell
parameter refinements showed that these parameters were
larger for S2 than those for S1. Photoluminescence and
ultraviolet visible spectra of the synthesized nanomaterials
were also investigated.
Keywords :
La2Ce2O7 , Hydrothermal , Nano , materials PXRD
Journal title :
Astroparticle Physics