Title of article :
Lanthanum cerate (La2Ce2O7): hydrothermal synthesis, characterization and optical properties
Author/Authors :
Khademinia, Shahin Department of Chemistry - Semnan University , Behzad, Mahdi
Pages :
7
From page :
101
To page :
107
Abstract :
La2Ce2O7 nano-powders were synthesized via a hydrothermal reaction in a deionized water (S1) and in a 2 M NaOH aqueous solution (S2) at 180 C for 48 h. La(NO3)3H2O and (NH4)2Ce(NO3)6 were used in the stoichiometric 1:1 La:Ce molar ratio as raw materials. The obtained materials were crystallized in a cubic crystal structure with space group. The synthesized materials were characterized by powder X-ray diffraction technique and Fourier-transform infrared spectroscopy. To investigate the effect of the basic solution on the morphology of the obtained materials, the morphologies of the synthesized materials were studied by field emission scanning electron microscopy technique. The technique showed that the morphology of La2Ce2O7 samples changed from grain to rod-like structure in presence of the basic solution. Cell parameter refinements showed that these parameters were larger for S2 than those for S1. Photoluminescence and ultraviolet visible spectra of the synthesized nanomaterials were also investigated.
Keywords :
La2Ce2O7 , Hydrothermal , Nano , materials PXRD
Journal title :
Astroparticle Physics
Serial Year :
2015
Record number :
2478258
Link To Document :
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