Title of article :
Synthesis, Spectroscopy and X-ray Crystallography Structure of Pyridine 4-Carbaldehyde Semicarbazone Schiff Base Ligand
Author/Authors :
Mahmoudi ، Farzaneh Department of Chemistry - Lorestan University , Farhadi ، Saeed Department of Chemistry - Lorestan University , Dusek ، Michal Institute of Physics - Czech Academy of Sciences , Poupon ، Morgane Institute of Physics - Czech Academy of Sciences
Abstract :
In this work, pyridine 4-carbaldehye semicarbazone Schiff base ligand (HL) was synthesized with condention of pyridine 4-carbaldehyde and semicarbazide hydrochloride in reflux method. The HL was characterized using the CHN elemental analysis, FT-IR, UV-Vis, and 1H NMR spectroscopy. The single crystals of HL prepared and used for the X-ray crystallography. Single-crystal X-ray diffraction revealed that, HL crystallized in a triclinic system with the space group P-1. The FT-IR spectra and X-ray crystallography results suggested that the HL ligand is in keto form.
Keywords :
Semicarbazone , Schiff base ligand , crystal structure , Spectroscopy
Journal title :
Advanced Journal of Chemistry, Section A: Theoretical, Engineering and Applied Chemistry
