Title of article :
Removal of Strontium Ions by Synthetic Nano Sodalite Zeolite from Aqueous Solution
Author/Authors :
Esfandiana, H. Gas and Petroleum - Semnan University, Semnan, Iran , Fakhraee, H. Malek-Ashtar University of Technology (MUT), Tehran, Iran , Azizi, A Department of Chemistry - Payame Noor University, Tehran, Iran
Abstract :
In this research, the zeolite sodalite, as an inorganic ion exchange material, was chemically produced in the template-free synthesis and evaluated in order to facilitate the sorption of strontium ions from aqueous solutions in batch operations onto acid treated zeolite with dilute H2SO4 solutions. The following indicates what the batch experiments included: a sorbent amount of 0.25 g in 100 mL of strontium solution (50 mg/L), a contact time of 80 min, pH 6 and a 20 oC temperature. To study the kinetics of removal process, three equations, i.e. Morris–Weber, Lagergren (pseudo first order) and pseudo second order were used. The sorption data were applied to the Langmuir, Freundlich, Dubnin-Randkovich (D-R) and Temkin models in order to estimate the sorption capacity, intensity and energy. An evaluation of the thermodynamic parameters ΔH, ΔS and ΔG was done. It was found out from thermodynamic parameters that the sorption of strontium onto zeolite was feasible, spontaneous and endothermic under studied conditions.
Farsi abstract :
در اﯾﻦ ﺗﺤﻘﯿﻖ، ﻧﺎﻧﻮ زﺋﻮﻟﯿﺖ ﺟﺪﯾﺪ ﺳﻮداﻟﯿﺖ ﺳﻨﺘﺰ ﺷﺪه و ﺳﺎﺧﺘﺎر زﺋﻮﻟﯿﺖ، ﺗﻮﺳﻂ آﻧﺎﻟﯿﺰﻫﺎي SEM ، XRD و FTIR ﻣﻮرد ﺑﺮرﺳﯽ ﻗﺮار ﮔﺮﻓﺘﻪ اﺳﺖ. زﺋﻮﻟﯿﺖ ﺳﺎﺧﺘﻪ ﺷﺪه ﺑﻪ ﻋﻨﻮان ﺟﺎذب در آزﻣﺎﯾﺸﺎت ﻧﺎﭘﯿﻮﺳﺘﻪ ﺟﺬب اﺳﺘﺮاﻧﺴﯿﻮم از ﻣﺤﻠﻮل آﺑﯽ ﺑﺮ روي زﺋﻮﻟﯿﺖ اﺳﯿﺪ ﺷﻮﯾﯽ ﺷﺪه ﺑﺎ اﺳﯿﺪ ﺳﻮﻟﻔﻮرﯾﮏ ﺑﮑﺎر ﺑﺮده ﺷﺪه اﺳﺖ ﺷﺮاﯾﻂ ﺑﻬﯿﻨﻪ ﺑﺪﺳﺖ آﻣﺪه ﺑﺮاي ﺟﺬب اﺳﺘﺮاﻧﺴﯿﻮم ﺗﻮﺳﻂ زﺋﻮﻟﯿﺖ ﺷﺎﻣﻞ 0/25 ﮔﺮم در 100 ﻣﯿﻠﯽ ﻟﯿﺘﺮ ﻣﺤﻠﻮل اﺳﺘﺮاﻧﺴﯿﻮم ) 50ppmزﻣﺎن ﺗﻌﺎدل، pH و دﻣﺎ ﺑﻪ ﺗﺮﺗﯿﺐ 80 دﻗﯿﻘﻪ، 6 و 20 درﺟﻪ ﺳﺎﻧﺘﯿﮕﺮاد ﺑﻮده اﺳﺖ. از ﻣﺪل ﻫﺎي ﺳﯿﻨﺘﯿﮑﯽ ﻣﻮرﯾﺲ وﺑﺮ، ﺷﺒﻪ ﻣﺮﺗﺒﻪ اول و ﺷﺒﻪ ﻣﺮﺗﺒﻪ دوم ﺑﺮاي ﺑﺮرﺳﯽ ﺳﯿﻨﺘﯿﮏ ﻓﺮآﯾﻨﺪ اﺳﺘﻔﺎده ﺷﺪ. ﻧﺘﺎﯾﺞ ﻧﺸﺎن داد ﺑﺮرﺳﯽ ﺳﯿﻨﺘﯿﮏ ﺟﺬب اﺳﺘﺮاﻧﺴﯿﻮم ﺗﻮﺳﻂ زﺋﻮﻟﯿﺖ ﻧﺸﺎن داد ﮐﻪ داده ﻫﺎي آزﻣﺎﯾﺸﮕﺎﻫﯽ ﺑﻬﺘﺮﯾﻦ ﺗﻄﺎﺑﻖ را ﺑﺎ ﻣﺪل ﺳﯿﻨﺘﯿﮑﯽ ﺷﺒﻪ درﺟﻪ دوم دارﻧﺪ. ﻫﻤﭽﻨﯿﻦ ﻣﻄﺎﻟﻌﻪ ﻣﺪل ﻫﺎي اﯾﺰوﺗﺮم ﺗﻮﺳﻂ ﭼﻬﺎر اﯾﺰوﺗﺮم ﻻﻧﮕﻤﯿﺮ، ﻓﺮﻧﺪﻟﯿﭻ، داﺑﯿﻨﯿﻦ رادﺷﮑﻮﯾﭻ و ﺗﻤﮑﯿﻦ ﺟﻬﺖ ﺑﺮرﺳﯽ ﻣﮑﺎﻧﯿﺰم ﺟﺬب اﺳﺘﺮاﻧﺴﯿﻮم ﺗﻮﺳﻂ زﺋﻮﻟﯿﺖ ﻧﺸﺎن داد ﮐﻪ اﯾﻦ ﻓﺮآﯾﻨﺪﻫﺎ ﺷﺎﻣﻞ واﮐﻨﺶ ﺟﺬب ﻓﯿﺰﯾﮑﯽ ﻣﯽ ﺑﺎﺷﻨﺪ.ﻣﻘﺎدﯾﺮ ﭘﺎراﻣﺘﺮﻫﺎي ﺗﺮﻣﻮدﯾﻨﺎﻣﯿﮑﯽ HA ، SA و GA ﻣﺤﺎﺳﺒﻪ ﺷﺪ. ﻧﺘﺎﯾﺞ اﻣﮑﺎن ﭘﺬﯾﺮ، ﺧﻮد ﺑﻪ ﺧﻮدي و ﮔﺮﻣﺎﮔﯿﺮ ﺑﻮدن واﮐﻨﺶ ﺟﺬب اﺳﺘﺮاﻧﺴﯿﻮم از ﻣﺤﻠﻮل آﺑﯽ ﺗﻮﺳﻂ زﺋﻮﻟﯿﺖ را ﻧﺸﺎن داد
Keywords :
Strontium , Sodalite Zeolite , Kinetic , Isotherm , Thermodynamic
Journal title :
International Journal of Engineering