Title of article :
Uranium Ions Removal Using Amberlite CG-400 Anion Exchanger Resin in the Presence of Sulfate Anions
Author/Authors :
Kosaria, M. Department of Energy Engineering - Sharif University of Technology, Tehran, Iran , Sepehrian, H. Nuclear Science and Technology Research Institute, Tehran, Iran , Outokesha, M. Department of Energy Engineering - Sharif University of Technology, Tehran, Iran , Fasihib, J. Nuclear Science and Technology Research Institute, Tehran, Iran , Mahanic, M. Department of Chemistry - Graduate University of Advanced Technology, Kerman, Iran
Pages :
7
From page :
728
To page :
734
Abstract :
Uptake of uranium (VI) ions using an anion exchanger resin, namely amberlite CG-400, was studied through this work in the presence of sulfate anions. Impact of various parameters including pH, contact time, initial concentration of uranium ions and intrusion with different anion contents (phosphate, chloride,sulfate, nitrate and fluoride) was examined on the sorption performance of the resin. An estimation of sorption process was also performed using isotherm and kinetics equations, which led to conformity of Freundlich and pseudo second-order models with experimental data, respectively. The maximum adsorption capacity (qmax) was found to be 63.29 mg g-1. Presence of various anions species in solution show that uranium sorption using amberlite CG-400 anion exchange resin could strongly be affected.
Farsi abstract :
ﺟﺬب ﯾﻮنﻫﺎي اوراﻧﯿﻮم )VI( ﺑﺎ اﺳﺘﻔﺎده از ﯾﮏ رزﯾﻦ ﺗﺒﺎدﻟﮕﺮ آﻧﯿﻮﻧﯽ، 400-Amberlite CG، در ﺣﻀﻮر آﻧﯿﻮن ﻫﺎي ﺳﻮﻟﻔﺎت در اﯾﻨﺠﺎ ﻣﻮرد ﻣﻄﺎﻟﻌﻪ ﻗﺮار ﮔﺮﻓﺘﻪ اﺳﺖ. اﺛﺮ ﭘﺎراﻣﺘﺮﻫﺎي ﻣﺨﺘﻠﻔﯽ ﺷﺎﻣﻞ pH، زﻣﺎن ﺗﻤﺎس، ﻏﻠﻈﺖ اوﻟﯿﻪ ﯾﻮن ﻫﺎي اوراﻧﯿﻮم و ﻣﺰاﺣﻤﺖ ﻣﺤﺘﻮاي آﻧﯿﻮﻧﯽ ﻣﺨﺘﻠﻒ )ﻓﺴﻔﺎت، ﮐﻠﺮﯾﺪ، ﺳﻮﻟﻔﺎت، ﻧﯿﺘﺮات و ﻓﻠﻮﺋﻮر( ﺑﺮ روي رﻓﺘﺎر ﺟﺬﺑﯽ رزﯾﻦ آزﻣﺎﯾﺶ ﺷﺪه اﺳﺖ. ﻧﺘﺎﯾﺞ ﻧﺸﺎن داد ﮐﻪ ﺟﺬب اوراﻧﯿﻮم ﺑﺮ روي رزﯾﻦ ﺑﻪ ﺻﻮرت ﻗﺎﺑﻞ ﺗﻮﺟﻬﯽ در pH=4 و ﺑﺎﻻﺗﺮ رخ ﻣﯽ دﻫﺪ. ﺳﯿﻨﺘﯿﮏ ﺟﺬب ﯾﻮن ﻫﺎي اوراﻧﯿﻮم ﺑﺴﯿﺎر ﺳﺮﯾﻊ ﺑﻮده و درﺻﺪ ﺟﺬب اوراﻧﯿﻮم در ﻣﺪت زﻣﺎن ﮐﻮﺗﺎﻫﯽ ﺑﻪ ﺑﯿﺸﺘﺮﯾﻦ ﻣﻘﺪار ﺧﻮد رﺳﯿﺪ. ﺗﺨﻤﯿﻦ ﻓﺮآﯾﻨﺪ ﺟﺬب ﺑﺎ اﺳﺘﻔﺎده از داده ﻫﺎي اﯾﺰوﺗﺮﻣﺎل و ﺳﯿﻨﺘﯿﮏ اﻧﺠﺎم ﮔﺮدﯾﺪ ﮐﻪ ﺑﻪ ﺗﺮﺗﯿﺐ ﺑﻪ ﺗﻄﺎﺑﻖ ﻣﺪل ﻫﺎي ﻓﺮوﻧﺪﻟﯿﭻ و ﺷﺒﻪ درﺟﻪ دوم ﺑﺎ داده ﻫﺎي آزﻣﺎﯾﺸﯽ ﻣﻨﺘﺞ ﺷﺪ. ﺑﯿﺸﺘﺮﯾﻦ ﻇﺮﻓﯿﺖ ﺟﺬب )qmax( ﺑﺮاﺑﺮ ﺑﺎ -mg g 63.29 ﺑﻮد. ﺣﻀﻮر ﮔﻮﻧﻪ ﻫﺎي آﻧﯿﻮﻧﯽ ﻣﺨﺘﻠﻒ در ﻣﺤﻠﻮل ﻧﺸﺎن ﻣﯽ دﻫﺪ ﮐﻪ ﺟﺬب اوراﻧﯿﻮم ﺑﺎ اﺳﺘﻔﺎده از رزﯾﻦ ﺗﺒﺎدﻟﮕﺮ آﻧﯿﻮﻧﯽ 400-Amberlite CG ﻣﯽ ﺗﻮاﻧﺪ ﺗﺎ ﺣﺪ زﯾﺎدي ﺗﺤﺖ ﺗﺎﺛﯿﺮ ﻗﺮار ﺑﮕﯿﺮد. ﺣﻀﻮر ﯾﻮن ﻫﺎي ﺳﻮﻟﻔﺎت در ﻣﺤﻠﻮل ﺑﺎﻋﺚ اﻓﺰاﯾﺶ ﺟﺬب ﮔﻮﻧﻪ ي اوراﻧﯿﻮم ﺗﻮﺳﻂ رزﯾﻦ ﻣﯽ ﮔﺮدد. ﯾﻮن ﻫﺎي ﻓﺴﻔﺎت در ﺟﺬب ﯾﻮن ﻫﺎي اوراﻧﯿﻮم ﻫﯿﭻ ﮔﻮﻧﻪ ﺗﺪاﺧﻠﯽ اﯾﺠﺎد ﻧﮑﺮده، اﻣﺎ ﺣﻀﻮر ﯾﻮﻧﻬﺎي ﻓﻠﻮﺋﻮرﯾﺪ، ﻧﯿﺘﺮات و ﮐﻠﺮﯾﺪ در ﻣﺤﻠﻮل ﺑﺎﻋﺚ ﮐﺎﻫﺶ ﻗﺪرت ﺟﺬب رزﯾﻦ ﻣﯽ ﮔﺮدد.
Keywords :
Uranium , Sorption , Amberlite CG-400 , Anion Exchanger Resin , Heavy Metals
Journal title :
International Journal of Engineering
Serial Year :
2016
Record number :
2507528
Link To Document :
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