Title of article :
Fe(HSO4)3-Catalyzed Direct Conversion of Aldehydes into Nitriles Using Hydroxylamine Hydrochloride
Author/Authors :
Taheri, Hassan Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad , Shiri, Ali Department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad , Eshghi, Hossein department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad , Sheikhi-Mohammareh, Seddigheh department of Chemistry - Faculty of Science - Ferdowsi University of Mashhad
Abstract :
Due to the importance and various applications of nitriles especially in medicinal productions, a new method for conversion of aldehydes to nitriles has been presented. Several nitrile-containing aromatic compounds were synthesized through the treatment of various aldehydes and hydroxylamine hydrochloride as nucleophile in the presence of ferric hydrogen sulfate as a heterogeneous, efficient, and recyclable catalyst in DMF in good to excellent yields.
Keywords :
hydroxylamine hydrochloride , Ferric hydrogen sulfate , Nitriles , Aldehydes
Journal title :
Organic Chemistry Research