Title of article :
Synthesis, spectroscopic characterization, mass spectrometry, and crystal structure of N-{[(4-bromophenyl)amino]carbonothioyl}benzamide
Author/Authors :
SAEED, Sohail Allama Iqbal Open University - Department of Chemistry, Research Complex, PAKISTAN , Rashid, Naghmana Allama Iqbal Open University - Department of Chemistry, Research Complex, Pakistan , BHATTI, Moazzam Hussain Allama Iqbal Open University - Department of Chemistry, Research Complex, PAKISTAN , JONES, Peter G. Technische Universitat Braunschweig - Institut fur Anorganische und Analytische Chemie, GERMANY
Abstract :
N-{[(4-bromophenyl)amino]carbonothioyl}benzamide was synthesized and characterized by IR, 1^H- and 13^C-NMR, mass spectrometry, and elemental analysis. The crystal structure was determined from single crystal X-ray diffraction data. It crystallizes in monoclinic space group P2_1 /n with unit cell dimensions a = 13.822(3) ˚A, b = 5.927(2) ˚A, c = 16.642(3) ˚A, and β = 103.963(3) ° . There is a strong intramolecular hydrogen bond of the type N-HΛO, with an HΛO distance of 2.6129 (11) ˚A. The mass fragmentation pattern is also discussed.
Keywords :
Thiourea derivative , X , ray structure determination , mass fragmentation
Journal title :
Turkish Journal of Chemistry
Journal title :
Turkish Journal of Chemistry
