Title of article :
An e cient ligand-free method for the transfer hydrogenation of ketones and aldehydes catalyzed by di erent complexes
Author/Authors :
YASAR, Sedat Gaziosmanpasa University - Faculty of Science and Arts - Department of Chemistry, Turkey , CEKIRDEK, Suzan Gaziosmanpasa University - Faculty of Science and Arts - Department of Chemistry, Turkey , AKKUS TAS, Nilay Gaziosmanpasa University - Faculty of Science and Arts - Department of Chemistry, Turkey , YILDIRIM, Semiha Karabuk University - Faculty of Science - Department of Chemistry, Turkey , OZDEMIR, Ismail Inonu University - Faculty Science and Arts - Chemistry Department, TURKEY
Abstract :
A very e cient ligand-free method was developed for the transfer hydrogenation of ketones and aldehydes catalyzed by di erent metal complexes. With this catalytic system, the catalytic performance and catalytic stability of di erent Ir, Ru, and Pd complexes were more favorable than those of the previously reported systems for transfer hydrogenation. This ligand-free catalytic system showed good stability and excellent activity even with lower catalyst concentrations for the ketones and aldehydes tested.
Keywords :
Transfer hydrogenation , ruthenium , iridium , palladium , ketone , aldehyde
Journal title :
Turkish Journal of Chemistry
Journal title :
Turkish Journal of Chemistry
