Title of article :
Novel metal-free and metallophthalocyanines containing four 21-membered pentathiadiaza macrocycles: synthesis, characterization, and study of aggregation properties
Author/Authors :
GÖK, Halil Zeki Osmaniye Korkut Ata University - Faculty of Arts and Sciences - Department of Chemistry, Turkey , FARSAK, Berna Osmaniye Korkut Ata University - Faculty of Arts and Sciences - Department of Chemistry, Turkey , KELEŞ, Hülya Osmaniye Korkut Ata University - Faculty of Arts and Sciences - Department of Chemistry, Turkey , KELEŞ, Mustafa Osmaniye Korkut Ata University - Faculty of Arts and Sciences - Department of Chemistry, Turkey
Abstract :
Metal-free phthalocyanine 3 and its metallophthalocyanine derivatives 4, 5, and 6 (M = Zn, Co, and Ni) substituted with four 21-membered pentathiadiaza macrocycles were synthesized and their structures identified by elemental analysis, IR, 1H NMR, mass, and UV-Vis spectroscopy techniques. The aggregation properties of phthalocyanines 4, 5, and 6 were investigated in different solvents and at different concentrations of dimethylformamide.
Keywords :
Macrocycle , aggregation , metal , free phthalocyanine , metallophthalocyanine
Journal title :
Turkish Journal of Chemistry
Journal title :
Turkish Journal of Chemistry