Author/Authors :
salah, merah tlemcen university - faculty of science - department of chemistry, laboratory of analytical chemistry and electrochemistry, Tlemcen, Algeria , salah, merah sai‹da university - faculty of technology - department of process engineering, Sai‹da, Algeria , lahce`ne, larabi tlemcen university - faculty of science - department of chemistry, laboratory of analytical chemistry and electrochemistry, Tlemcen, Algeria , omar, abderrahim tlemcen university - faculty of science - department of chemistry, laboratory of separation and purification technology, Tlemcen, Algeria , yahia, harek tlemcen university - faculty of science - department of chemistry, laboratory of analytical chemistry and electrochemistry, Tlemcen, Algeria
Abstract :
A new class of corrosion inhibitors, namely, polyethyleneiminemethylene phosphonic acid (PEIMPA), was synthesized and its inhibiting action on the corrosion of C38 steel in 1 M HCl at 30 ◦C was investigated by various corrosion monitoring techniques such as weight loss measurements, potentiodynamic polarization, linear polarization resistance (Rp), and surface analysis (SEM and EDX) which are used to characterize the steel surface. Weight loss measurements revealed that the presence of PEIMPA increases the inhibition efficiency by decreasing the corrosion rate. Tafel polarization study showed that the inhibitor acts as a mixed-type inhibitor. Adsorption of PEIMPA on the carbon steel surface was found to obey the Langmuir isotherm. Some thermodynamic functions of dissolution and adsorption processes were also determinedand discussed. The SEM results showed the formation of protective film on the mild steel surface in the presence of PEIMPA. The results obtained from different tested techniques were in good agreement.
Keywords :
Corrosion , Inhibition , C38 steel , Phosphonic acid
