Zinc(II) selectivepoly(vinyl chloride) membrane ISE using a macrocyclic compound 1,12,14-triaza-5,8-dioxo-3(4),9(10)- dibenzoylcyclopentadeca-1,12,14-triene as neutral carrier

The potentiometric response characteristics of zinc ion selective PVC-based membrane electrode employing 1,12,14-triaza-5,8-dioxo-3(4),9(10)-dibenzoyl-1,12,14-triene as an inophore was investigated. The proposed electrode exhibits a Nernstian behavior with a slope of 29.2 ± 0.4 mV per decade with a working concentration range of 1.3 × 10^-7–1.0 × 10^-1 mol L^-1 and a detection limit of 1.0 × 10^-8 mol L^-1. The membrane having the composition as TDODBCPT:O-NPOE:PVC:OA; 7:57:30:6 wt.% exhibits the best results. It has a fast response time of 7 s and can be used for at least 100 days without any considerable divergence in potential. The proposed electrode show good discrimination of Zn^2+ ion from diverse ions. The potential response remains constant over a pH range of 3.5–9.2. The electrode found well work under laboratory conditions. The proposed sensor directly used for determination of zinc ions in human hair sample, wastewater and an indicator electrode with EDTA titration.