Title of article :
Bis(Alkyne) Copper(I) Trifluoracetate: Synthesis, Characterization, and Solid-State Structure
Author/Authors :
Al-Anber, Mohammed A. Mu´tah University - Faculty of Science - Department of Chemical Science, Jordan , Walfort, Bernhard Technische Universitat Chemnitz - Institut fur Chernie - Lehrstuhl fur Anorganische Chemie, Germany , Lang, Heinrich Technische Universitat Chemnitz - Fakultät für Naturwissenschaften, Institut fur Chernie - Lehrstuhl fur Anorganische Chemie, Germany
Abstract :
Heterobimetallic {[Ti](μ-σ,π-C≡CSiMe3)2}CuO2CCF3 (3) ([Ti] = (η5-C5H4SiMe3)2Ti) was synthesized by reacting the organometallic π-tweezer molecule [Ti](C≡CSiMe3)2 (1) with stoichiometric amounts of 1/n[CuO2CCF3]n (2). The structure of 3 in the solid state was determined by single X-ray structure analysis indicating that a mononuclear copper(I) carboxylate unit with a tri-coordinated copper atom is present. Within this building block the titanium alkynyl ligands are chelate-bonded to the group-11 metal atom.
Keywords :
Heterobimetallic , Organometallic π , Tweezer , Titanium , Copper(I) Trifluoroacetate , X , ray Structure
Journal title :
Jordan Journal of Chemistry
Journal title :
Jordan Journal of Chemistry
