Title of article :
Hydrolysis of Thallium Phthalimide. The Crystal Structure of Dimorph Polymeric Thallium(I) Complex, {Tl[(Hphthalate)]}n
Author/Authors :
Abu-Salem, Qutaiba Al al-Bayt University - Faculty of Science - Department of Chemistry, Jordan , Mallah, Eyad Petra University - Faculty of Pharmacy and Medical Sciences, Jordan , Said, Farouq F. Al al-Bayt University - Faculty of Science - Department of Chemistry, Jordan , Ali, Basem F. Al al-Bayt University - Faculty of Science - Department of Chemistry, Jordan , Steinmann, Manfred University of Tübingen - Institute for Inorganic Chemistry, Germany , Voelter, Wolfgang University of Tübingen - Interfacultary Institute of Biochemistry, Germany
Abstract :
Single crystals of [Tl(Hphthalate)]n, were grown by hydrolysis of thallium phthalimide during slow evaporation of an aqueous solution at room temperature, and the structure was determined by X-ray diffraction analysis. It has been characterized also by elemental analysis,NMR, and IR spectroscopy. The crystals belong to the monoclinic crystal system space groupP21/c. its crystal structure analysis reveals that there is (TlO6) six coordinate Tl atoms. Inaddition, the coordination geometry of Tl^+ may be influenced by its stereochemically active lone pair. The complex is linked via intermolecular O-H···O hydrogen bonding.
Keywords :
Hydrogen Bond , Crystal Structure , Thallium, Phthalate Ligand.
Journal title :
Jordan Journal of Chemistry
Journal title :
Jordan Journal of Chemistry
