Title of article :
Synthesis and Spectroscopic of Some new Metal Ions Complexes s with [N-(4-Methoxy Benzoyl Amino)-Thioxo Methyl] Leucine
Author/Authors :
Sarhan, Basima M. University of Baghdad - College of Education For Pure Science(Ibn-Al Haitham) - Chemistry Department, Iraq , Fayyadh, Bushra M. University of Baghdad - College of Education For Pure Science(Ibn-Al Haitham) - Dept of Chemistry, Iraq , Hassan, Hassan A. Baghdad University - College of Education For Pure Science(Ibn-Al Haitham) - Dept of Chemistry, Iraq
Abstract :
A new ligand [N-(4-methoxy benzoyl amino)-thioxo methyl ] leucine (MBL) was prepared from the reaction of (4-methoxy benzoyl isothiocyanate with leucine acid in molar ratio (l:l), it was characterized by elemental analysis (C.H.N.S), FT-IR, UV-Vis, 1H and 13C-NMR. The complexes of the bivalent ions (Mn, Fe, Co, Ni, Cu, Zn, Cd and Hg ) have been prepared and characterized too. The structural was established by elemental analysis (C.H.N.S), FT-IR, UV-Vis spectra, conductivity measurements atomic absorption and magnetic susceptibility and determination of molar ration (M:L). The complexes showed characteristic behavior of tetrahedral geometry around the metal ions except with (Cu) complex showed square planer.
Keywords :
4 , Methoxy benzoyl isothiocyanate , leucine , complexes.
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science
