Title of article
Physicochemical Characteristics of Malaysian Crude Palm Kernel Oil
Author/Authors
Bahadi, Murad Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia - Faculty of Education - Hadhramout University - Hadhramout, Yemen , Firdaus Mohamad Yusoff, Mohamad Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia , Salimon, Jumat Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia , Ahmed Jumaah, Majd Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia , Derawi, Darfizzi Laboratory for Biolubricant - Biofuels and Bioenergy Research - Centre for Advanced Materialsand Renewable Resources - Faculty of Science and Technology - Universiti Kebangsaan Malaysia - 43600 UKM Bangi - Selangor, Malaysia
Pages
11
From page
17
To page
27
Abstract
This study was carried out to determine the physicochemical properties of Malaysian crudepalm kernel oil (CPKO). The physicochemical properties showed that the free fatty acid(FFA%) of 3.7±0.1%, acid value of 10.4±0.1 mg/g, iodine value of 20.8±0.6 mg/g, hydroxylvalue of 45.06±0.3 mg/g, refractive index at 28°C of g/ml, 1.455, moisturecontent of0.5±0.1%, viscosity at 28°C of 40 cP, Lovibond colour (R/Y) at 28°C of 0.5R–20Y. The gaschromatography-flame ionisation detector was used to determine the fatty acid composition inCPKO. The results showed that the dominant fatty acids are lauric acid (44.5±0.7%), oleic acid(18.0±0.5%), myristic acid (16.9±0.1%) and palmitic acid (9.4±0.2%). The majortriacylglycerols (TAGs) of CPKO estimated using high-performance liquid chromatographywere LaLaLa (32.91%), LaLaM (23.59), LaOLa (9.93%) and CLaLa (9.10%). The differentialscanning calorimetry showed that the crystallisation of CPKO displayed two major exothermicregions of CPKO with the saturated TAG at 6.11°C and the unsaturated TAG at-2.10°C. Themelting curve of CPKO displayed two endothermicpeak regions at 9.13°C and 24.08°C.
Keywords
crude palm kernel oil , physicochemical characteristic , triacylglycerol profile , fatty acid composition , thermal behaviour
Journal title
Malaysian Journal of Chemistry
Serial Year
2019
Full Text URL
Record number
2599061
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