Title of article
Synthesis and Characterisation of Novel Cobalt(II),Copper (II) and Mercury (II) Complexes of Poly Vinyl Urethanised Oxime.
Author/Authors
Al-Jeboori, M. J. Ibn AIHaitham Haitham - College of Education - Department of Chemistry, Iraq , Numan, A. T. , Ahmed, D. J. University of Baghdad - College of Education, Ibn AIHaitham - Department of Chemistry, Iraq
From page
89
To page
101
Abstract
The reaction of poly (vinyl alcohol) (PVA) with Urea in (DMSO) resulted in uerthanised oxim, which reacted with diacetylmonoxime in a (DMSO/methanol) to give anew type (N2) polymeric bidentate imine oxime ligand [HL], The ligand was reacted with MC12 (where M= Co, Cu, and Hg). Under reflux in a (DMF/Methanol) mixture with (1:1) ratio to give Complexes of the general formula [M (L)2]X, (where M= Co,Hg, Cu). All compounds have been characterized by spectroscopic methods [IR, U.V.-Vis, Atomicabsorption] microanalysis along with conductivity measurements, from the above data the proposed molecular structure for Co,Cu, and Hg is a distorted. Tetrahedral
Journal title
Ibn Alhaitham Journal For Pure and Applied Science
Journal title
Ibn Alhaitham Journal For Pure and Applied Science
Record number
2601316
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