Title of article :
Synthesis and Characterisation of Novel Cobalt(II),Copper (II) and Mercury (II) Complexes of Poly Vinyl Urethanised Oxime.
Author/Authors :
Al-Jeboori, M. J. Ibn AIHaitham Haitham - College of Education - Department of Chemistry, Iraq , Numan, A. T. , Ahmed, D. J. University of Baghdad - College of Education, Ibn AIHaitham - Department of Chemistry, Iraq
Abstract :
The reaction of poly (vinyl alcohol) (PVA) with Urea in (DMSO) resulted in uerthanised oxim, which reacted with diacetylmonoxime in a (DMSO/methanol) to give anew type (N2) polymeric bidentate imine oxime ligand [HL], The ligand was reacted with MC12 (where M= Co, Cu, and Hg). Under reflux in a (DMF/Methanol) mixture with (1:1) ratio to give Complexes of the general formula [M (L)2]X, (where M= Co,Hg, Cu). All compounds have been characterized by spectroscopic methods [IR, U.V.-Vis, Atomicabsorption] microanalysis along with conductivity measurements, from the above data the proposed molecular structure for Co,Cu, and Hg is a distorted. Tetrahedral
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science
