Title of article :
Synthesis and Characterization of Transition Metals Ions Complexes with 2-Thioxoimidazolidin-4-One Schiff Base as Ligand
Author/Authors :
al-bayati, sinan midhat al-mustansiriyah university - college of science - dept. of chemistry, Iraq , rasheed, anaam majeed al-mustansiriyah university - college of science - department of chemistry, Iraq , mohammed, enas zuhair al-mustansiriyah university - college of science - dept. of chemistry, Iraq , hassan, zeina kudair al-mustansiriyah university - college of science - dept. of chemistry, Iraq , chali, amjad al-mustansiriyah university - college of science - dept. of chemistry, Iraq , hussein, amal mohammed al-mustansiriyah university - college of science - dept. of chemistry, Iraq
Abstract :
Mn(II), Co(II), Ni(II), Cu(II), and Cr(III) metal complexes with the ligand (L) [3-(2-nitro benzylidene) amino-2-thioxoimidazolidin-4-one] have been prepared and characterized in their solid state using the elemental micro analysis (C.H.N.S), flame atomic absorption, UV-Vis spectroscopy, FT-IR, magnetic susceptibility measurements, and electrical molar conductivity. The ratio of metal to ligand [M:L] was got for all complexes in the ethanol by using the molar ratio method, which produced comparable results with those results obtained for the solid complexes. From the data of all techniques, octahedral geometry was proposed for Cr(III), Mn(II), and Co(II) complexes, while tetrahedral structure was proposed for Ni(II), Cu(II) complexes.
Keywords :
Synthesis , Characterization , Bidentate Schiff Base , Transition Metal Complexes
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science
Journal title :
Ibn Alhaitham Journal For Pure and Applied Science
