Title of article :
Crystal structure of N-{4-[(6-chloropyridin-3-yl)- methoxy]phenyl}-2,6-difluorobenzamide
Author/Authors :
Liang,Ying Hubei Biopesticide Engineering Research Center - Hubei Academy of Agricultural Science, People’s Republic of China. , Shi, Li-Qiao Hubei Biopesticide Engineering Research Center - Hubei Academy of Agricultural Science, People’s Republic of China. , Yang, Zi-Wen Hubei Biopesticide Engineering Research Center - Hubei Academy of Agricultural Science, People’s Republic of China.
Pages :
8
From page :
1
To page :
8
Abstract :
In the title compound, C19H13ClF2N2O2, the conformation of the N—H bond in the amide segment is anti to the C O bond. The molecule is not planar, with dihedral angles between the central benzene ring and the outer benzene and pyridyl rings of 73.35 (7) and 81.26 (6), respectively. A weak intramolecular C— HO hydrogen bond occurs. In the crystal, N—HN, C—HO and C— HF hydrogen bonds lead to the formation of dimers. The N—HN inversion dimers are linked by – contacts between adjacent pyridine rings [centroid– centroid = 3.8541 (12) A˚ ] and C—H interactions. These contacts combine to stack the molecules along the a axis.
Keywords :
contacts , crystal structure , hydrogen bonding , pyridine , amide derivative
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2016
Full Text URL :
Record number :
2614486
Link To Document :
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