Title of article :
Crystal structure of 1,2-bis((benzylsulfanyl){2-[1-(2-hydroxyphenyl)ethylidene]hydrazin-1-ylidene}methyl)disulfane
Author/Authors :
Islam, M. A. A. A. A. Department of Chemistry - Rajshahi University of Engineering & Technology, Bangladesh , Sheikh, M. C. Department of Applied Chemistry - Faculty of Engineering, University of Toyama, Japan , Islam, M. H. Department of Chemistry - Rajshahi University of Engineering & Technology, Bangladesh , Miyatake, R. Center for Environmental Conservation and Research Safety - University of Toyama, Japan , Zangrando, E. Department of Chemical and Pharmaceutical Sciences, Italy
Abstract :
The title compound, C32H30N4O2S4, consists of two Schiff base moieties, namely two S-benzyl-β-N-(2-hydroxyphenylethylidene)dithiocarbazate groups, which are connected through an S—S single bond. These two moieties are twisted with respect to each other, with a dihedral angle of 87.88 (4)° between the S2C=N planes. A bifurcated intramolecular O—H⋯(N,S) hydrogen bond is observed in each moiety. In the crystal, molecules are linked by pairs of C—H⋯O hydrogen bonds into inversion dimers. The dimers are further stacked in a column along the b axis through weak C—H⋯π interactions.
Keywords :
hydrogen bond , hydroxyphenylethylidene , dithiocarbazate , Schiff base , crystal structure
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
