Title of article :
Crystal structure of dichloridobis(dimethyl N-cyanodithioiminocarbonate)zinc
Author/Authors :
Diop, Mouhamadou Birame Laboratoire de Chimie Minérale et Analytique - Département de Chimie, Faculté des Sciences et Techniques - Université Cheikh Anta Diop, Dakar, Senegal , Diop, Libasse Laboratoire de Chimie Minérale et Analytique - Département de Chimie, Faculté des Sciences et Techniques - Université Cheikh Anta Diop, Dakar, Senegal , Oliver, Allen G. Department of Chemistry and Biochemistry - University of Notre Dame, USA
Abstract :
The ZnII atom in the title complex, [ZnCl2(C4H6N2S2)2], is coordinated in a distorted tetrahedral manner by two Cl atoms and two terminal N atoms of two dimethyl N-cyanodithioiminocarbonate ligands. In the crystal, the complex molecules are connected through C—H⋯Cl hydrogen bonds and Cl⋯S contacts, leading to a two-dimensional structure extending parallel to the ab plane.
Keywords :
layered structure , tetrahedral environment , dimethyl N-cyanodithioiminocarbonate , zinc chloride adduct , crystal structure
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
