Title of article
Crystal structure of octakis(N,N-dimethylformamide-κO)europium(III) tetracosa-μ2-oxido-dodecaoxido-μ12-phosphato-dodecamolybdate(VI)
Author/Authors
Ghandour,Yassine Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Tunisia , Hammami, Imen Laboratoire de Physico-chimie des Matériaux, Faculté des Sciences de Monastir, Tunisia , Najmudin, Shabir aculdade de Medicina, Veterina`ria - Universidade Tecnica de Lisboa, Portugal , Bonifacio, Cecilia REQUIMTE/CQFB Departamento de Quimica - Faculdade de Ciencias e Tecnologia - Universidade Nova de Lisboa, Portugal
Pages
20
From page
1
To page
20
Abstract
In the title salt, [Eu(C3H7NO)8][PMo12O40], the asymmetric unit comprises one α-Keggin-type [PMo12O40]3− polyoxidometalate anion and one distorted dodecahedral [Eu(C3H7NO)8]3+ complex cation. In the crystal, the isolated polyoxidometalate anions are packed into hexagonally arranged rows extending parallel to [001]. The complex cations are situated between the rows and are linked to the neighbouring anions through weak C—H⋯O hydrogen-bonding interactions, leading to the formation of a three-dimensional network structure.
Keywords
crystal structure , IR spectroscopy , α-Keggin-type [PMo12O40]3− polyanion , europium
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2617573
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