Title of article :
Crystal structure of (E,E)-2′,4′-dihydroxyacetophenone azine dimethylformamide disolvate
Author/Authors :
Li, Wen-Juan Department of Chemistry - Taiyuan Normal University, People's Republic of China , Han, Hong-Fei Department of Chemistry - Taiyuan Normal University, People's Republic of China
Abstract :
In the title compound {systematic name: 4,4′-[1,1′-(hydrazinediylidene)bis(ethan-1-yl-1-ylidene)]bis(benzene-1,3-diol)}, C16H16N2O4·2C3H7NO, the (E,E)-2′,4′-dihydroxyacetophenone azine molecule is centrosymmetric, the mid-point of the N—N bond being located on an inversion centre. All the non-H atoms of the azine molecule are approximately coplanar, the maximum deviation being 0.017 (2) Å. An intramolecular O—H⋯N hydrogen bond occurs between the azine N atom and the hydroxy group. In the crystal, azine and dimethylformamide solvent molecules are linked by O—H⋯O hydrogen bonds.
Keywords :
(E,E)-2′,4′-dihydroxyacetophenone azine , crystal structure , hydrogen bond
Journal title :
Acta Crystallographica Section E: Crystallographic Communications