Title of article :
Crystal structure of (±)-[trans-cyclo­hexane-1,2-diylbis(aza­nedi­yl)]di­phospho­nium dibromide di­chloro­methane disolvate
Author/Authors :
A lvarez,Aurora Rodrı´guez Centro de Investigaciónes Químicas - Universidad Autónoma del Estado de Morelos, , Mexico , Tlahuext, Hugo Centro de Investigaciónes Químicas - Universidad Autónoma del Estado de Morelos, , Mexico , Grevy,Jean-Michel Centro de Investigaciónes Químicas - Universidad Autónoma del Estado de Morelos, , Mexico
Pages :
10
From page :
1
To page :
10
Abstract :
The cation of the title solvated salt, C42H42N2P22+·2Br−·2CH2Cl2, lies on a crystallographic twofold rotation axis. The 1,2-di­amino­cyclo­hexane fragment has a chair conformation with two N atoms in a transoid conformation [N—C—C—N = 163.4 (2)°]. In the crystal, the cations are linked to the anions by N—H⋯Br and C—H⋯Br hydrogen bonds, forming a chain structure along the c axis. The di­chloro­methane mol­ecule takes part in the hydrogen-bond network through C—H⋯π and C—H⋯Br inter­actions.
Keywords :
crystal structure , C—H⋯Br and C—H⋯π inter­actions , di­phospho­nium ligands , trans-di­amino­cyclo­hexa­ne
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2016
Full Text URL :
Record number :
2617768
Link To Document :
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