Title of article :
Crystal structure of 1,4-bis­­(3-ammonio­prop­yl)piperazine-1,4-diium bis­­[dichromate(VI)]
Author/Authors :
Vetrivel, S. PG & Research Department of Physics - Government Arts College, India , Vinoth, E. PG & Research Department of Physics - Government Arts College, India , Mullai, R. U. PG & Research Department of Physics - Government Arts College, India , Aruljothia, R. PG & Research Department of Physics - Government Arts College, India , NizamMohideenb, M. Department of Physics - The New College (Autonomous), India
Pages :
8
From page :
1
To page :
8
Abstract :
The asymmetric unit of the organic–inorganic title salt, (C10H28N4)[Cr2O7]2, comprises one half of an 1,4-bis­(3-ammonio­prop­yl)piperazinediium cation (the other half being generated by the application of inversion symmetry) and a dichromate anion. The piperazine ring of the cation adopts a chair conformation, and the two CrO4 tetra­hedra of the anion are in an almost eclipsed conformation. In the crystal, the cations and anions form a layered arrangement parallel to (001). N—H⋯O hydrogen bonds between the cations and anions and additional C—H⋯O inter­actions lead to the formation of a three-dimensional network structure.
Keywords :
hydrogen bonding , mol­ecular salt , piperazinediium cation , dichromate anion , crystal structure
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2016
Full Text URL :
Record number :
2617808
Link To Document :
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