• Title of article

    Crystal structure of bis­­(isonicotinamide-κN1)bis­­(thio­cyanato-κN)zinc

  • Author/Authors

    Neumann, Tristan Institut für Anorganische Chemie - Christian-Albrechts-Universität Kiel, Germany , Jess, Inke Institut für Anorganische Chemie - Christian-Albrechts-Universität Kiel, Germany , Näthera, Christian Institut für Anorganische Chemie - Christian-Albrechts-Universität Kiel, Germany

  • Pages
    7
  • From page
    1
  • To page
    7
  • Abstract
    The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn2+ cation located on a twofold rotation axis, as well as of one thio­cyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn2+ cation is tetra­hedrally coordinated into a discrete complex by the N atoms of two symmetry-related thio­cyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by inter­molecular C—H⋯O and N—H⋯O, and weak inter­molecular N—H⋯S hydrogen-bonding inter­actions into a three-dimensional network.
  • Keywords
    hydrogen bonding , crystal structure , isonicotinamide , zinc thio­cyanate , discrete complex
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2016
  • Record number

    2618337