Title of article :
Crystal structure of (E)-2-[(2-bromopyridin-3-yl)methyl­­idene]-6-meth­­oxy-3,4-di­hydro­naphthalen-1(2H)-one and 3-[(E)-(6-meth­­oxy-1-oxo-1,2,3,4-tetra­hydro­naphthalen-2-yl­idene)meth­yl]pyridin-2(1H)-one
Author/Authors :
Zingales, Sarah K. Armstrong State University, USA , Moore, Morgan E. Armstrong State University, USA , Goetz, Andrew D. Armstrong State University, USA , Padgett, Clifford W. Armstrong State University, USA
Pages :
23
From page :
1
To page :
23
Abstract :
The title compounds C17H14BrNO2, (I), and C17H15NO3, (II), were obtained from the reaction of 6-meth­oxy-3,4-di­hydro-2H-naphthalen-1-one and 2-bromo­nicotinaldehyde in ethanol. Compound (I) was the expected product and compound (II) was the oxidation product from air exposure. In the crystal structure of compound (I), there are no short contacts or hydrogen bonds. The structure does display π–π inter­actions between adjacent benzene rings and adjacent pyridyl rings. Compound (II) contains two independent mol­ecules, A and B, in the asymmetric unit; both are non-planar, the dihedral angles between the meth­oxy­benzene and 1H-pyridin-2-one mean planes being 35.07 (9)° in A and 35.28 (9)°in B. In each mol­ecule, the 1H-pyridin-2-one unit participates in inter­molecular N—H⋯O hydrogen bonding to another mol­ecule of the same type (A to A or B to B). The structure also displays π–π inter­actions between the pyridyl and the benzene rings of non-equivalent mol­ecules (viz., A to B and B to A).
Keywords :
crystal structure , chalcone , 3-[(E)-(6-Meth­oxy-3,4-di­hydro­naphth-2-oyl­idene)meth­yl]-1H-pyridin-2-one and (E)-2-[(2-bromo-3-pyrid­yl)methyl­idene]-6-meth­oxy-3,4-di­hydro­naphthalen-1-one
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2016
Full Text URL :
Record number :
2618358
Link To Document :
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