Title of article :
Crystal structure of racemic [(1R,2S,3R,4S,6S)-2,6-bis(furan-2-yl)-4-hydroxy-4-(thiophen-2-yl)cyclohexane-1,3-diyl]bis(thiophen-2-ylmethanone)
Author/Authors :
Çelik, smail Department of Physics - Faculty of Sciences - Cumhuriyet University,Turkey , Ersanlı, Cem Cuneyt Department of Physics - Faculty of Arts and Sciences - , Sinop University, Turkey , Akkurt, Mehmet Department of Physics - Faculty of Sciences - Erciyes University, Turkey , Gezegend , Hayreddin Department of Chemistry - Faculty of Sciences - Cumhuriyet University, Turkey , Ko seog lu, Rahmi Department of Physics - Faculty of Sciences - Erciyes University, Turkey
Abstract :
In the title compound, C28H22O5S3, the central cyclohexane ring adopts a chair conformation. The atoms of the furan ring attached to the 6-position of the central cyclohexane ring are disordered over two sets of sites with occupancies of 0.832 (5) and 0.168 (5). The hydroxy group is disordered over two positions (at the 4- and 6-positions of the cyclohexane ring) in the ratio 0.832 (5):0.168 (5). In the crystal, molecules are linked by C—H⋯O hydrogen bonds and C—H⋯π interactions, forming layers parallel to (100)
Keywords :
crystal structure , domino reactions , pentasubstituted cyclohexanol derivatives
Journal title :
Acta Crystallographica Section E: Crystallographic Communications