Title of article :
Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate1
Author/Authors :
Taouss, Christina Institut für Anorganische und Analytische Chemie - Technische Universität Braunschweig, Germany , Jones, Peter G. Institut für Anorganische und Analytische Chemie - Technische Universität Braunschweig, Germany
Abstract :
The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O—P⋯P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The AuI atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The molecules associate to form broad ribbons parallel to the c axis via two C—H⋯O, one C—H⋯Cl(Au) and one Au⋯Cl interaction.
Keywords :
crystal structure , gold , phosphine , chalcogenide
Journal title :
Acta Crystallographica Section E: Crystallographic Communications