Title of article :
Crystal structure of 9,9′-{(1E,1′E)-[1,4-phenyl­enebis(aza­nylyl­­idene)]bis­­(methanylyl­­idene)}bis­­(2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol)
Author/Authors :
Haque Faizi, Md. Serajul Department of Chemistry - College of Science, Sultan Qaboos University,Oman , Alib, Akram Department of Chemistry - Indian Institute of Technology Kanpur, India , Potaskalov, Vadim A. Department of General and Inorganic Chemistry - National Technical University of Ukraine - Kyiv Polytechnic Institute, Ukraine
Pages :
9
From page :
1
To page :
9
Abstract :
The whole mol­ecule of the title compound, C32H34N2O2, is generated by inversion symmetry; the central benzene ring being situated about the crystallographic inversion center. The aromatic ring of the julolidine moiety is inclined to the central benzene ring by 33.70 (12)°. There are two intra­molecular O—H⋯N hydrogen bonds in the mol­ecule, generating S(6) ring motifs. The conformation about the C=N bonds is E. The fused non-aromatic rings of the julolidine moiety adopt half-chair conformations. In the crystal, adjacent mol­ecules are linked by pairs of C—H⋯π inter­actions, forming a ladder-like structure propagating along the a-axis direction.
Keywords :
crystal structure , julolidine , Schiff base , 8-hy­droxy­julolidine-9-carboxaldehyde , p-phenyl­enedi­amine , C—H⋯π inter­actions , hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2016
Full Text URL :
Record number :
2618882
Link To Document :
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