• Title of article

    Crystal structure of (OC)5W(μ-dppe)W(CO)5

  • Author/Authors

    Drake, Hannah F. Department of Chemistry - Western Illinois University, USA , Wheeler, Kraig A. Department of Chemistry - Eastern Illinois University, Charleston, USA , Bellott, Brian J. Department of Chemistry - Western Illinois University, USA

  • Pages
    8
  • From page
    1
  • To page
    8
  • Abstract
    The centrosymmetric title complex, [μ-ethane-1,2-diylbis(di­phenyl­phosphane)-κ2P:P′]bis­[penta­carbonyl­tungsten(0)], [W2(C26H24P2)(CO)10], consists of two W(CO)5 moieties bridged by a bis­(di­phenyl­phosphan­yl)ethane (dppe) ligand. The W0 atom has a slightly distorted octa­hedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W0 atom 5.625 (5) Å away. The complex resides on a center of symmetry.
  • Keywords
    crystal structure , group 6 carbon­yl , bimetallic , bridging dppe
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2016
  • Full Text URL
    journals.iucr.org/e/issues/2016/10/00/vn2114/vn2114.pdf
  • Record number

    2618897

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2618897