Title of article :
Crystal structure of 1,3-bis[(E)-4-methoxybenzylideneamino]propan-2-ol
Author/Authors :
Rivera, Augusto Facultad de Ciencias - Departamento de Química, ColombUniversidad Nacional de Colombia, Sede Bogotá ia , Miranda-Carvajal, Ingrid Facultad de Ciencias - Departamento de Química, ColombUniversidad Nacional de Colombia, Sede Bogotá ia , Ríos-Motta, Jaime Facultad de Ciencias - Departamento de Química, ColombUniversidad Nacional de Colombia, Sede Bogotá ia , Bolte, Michael Institut für Anorganische Chemie - J. W. Goethe-Universität Frankfurt, Germany. -
Abstract :
The title Schiff base, C19H22N2O3, was synthesized via the condensation reaction of 1,3-diaminopropan-2-ol with 4-methoxybenzaldehyde using water as solvent. The molecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings is 37.25 (15)°. In the crystal, O—H⋯N hydrogen bonds link the molecules into infinite C(5) chains propagating along the a-axis direction. The packing of these chains is consolidated by C—H⋯O interactions and C—H⋯π short contacts, forming a three-dimensional network.
Keywords :
crystal structure , Schiff bases , hydrogen bonding , C—H⋯O interactions
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
