Author/Authors :
Kubono, Koji Division of Natural Sciences - Osaka Kyoiku University, Japan , Kise, Ryuma Division of Natural Sciences - Osaka Kyoiku University, Japan , Kashiwagib, Yukiyasu Osaka Municipal Technical Research Institute, Japan , Tani, Keita Division of Natural Sciences - Osaka Kyoiku University, Japan , Yokoi, Kunihiko Division of Natural Sciences - Osaka Kyoiku University, Japan
Abstract :
In the title compound, C15H18N2O3, the coumarin ring is essentially planar, with an r.m.s. deviation of 0.012 Å. An intramolecular O—H⋯N hydrogen bond forms an S(6) ring motif. The piperazine ring adopts a chair conformation. In the crystal, a C—H⋯O hydrogen bond generates a C(4) chain motif running along the c axis. The chain structure is stabilized by a C—H⋯π interaction. The chains are linked by π–π interactions [centroid–centroid distance of 3.5745 (11) Å], forming a sheet structure parallel to the bc plane.
Keywords :
crystal structure , π–π interactions. , hydrogen bonding , piperazine , coumarin