Title of article :
Crystal structure of catena-poly[diammonium [di-μ-oxalato-cuprate(II)]
Author/Authors :
Dickie, Diane A. Department of Chemistry and Chemical Biology, MSC03 2060 - 1 University of New Mexico, USA , Kempa, Richard A. Department of Chemistry and Chemical Biology, MSC03 2060 - 1 University of New Mexico, USA
Abstract :
The structure of the title compound, {(NH4)2[Cu(C2O4)2]}n, at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu⋯O interactions which create [Cu(C2O4)2] chains along the a axis. The structure also displays intermolecular N—H⋯O hydrogen bonding, which links these chains into a three-dimensional network.
Keywords :
crystal structure , ammonium , hydrogen bonding , copper , oxalate
Journal title :
Acta Crystallographica Section E: Crystallographic Communications